Excel blobs and BCP extract commands

If this is a new thing, and if you expect to have more than 10 thousand documents, or 10 GB of data, PLEASE DO NOT store them in blob columns in SQL Server. It will quickly become an administrative hassle.

My additional comments here:

The comment I made about PDFs not compressing also applies to XLSX files, they are already compressed, so your database backups will not get any benefit from backup compression.